当前位置：
X-MOL 学术
›
Cryst. Growth Des.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Tuning Emission Properties via Aromatic Guest Inclusion in Organic Salts Composed of 4,4′-Dinitro-2,2′,6,6′-tetracarboxybiphenyl and Acridine
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2018-01-04 00:00:00 , DOI: 10.1021/acs.cgd.7b01530 Abhijit Garai , Subhrajit Mukherjee , Samit K. Ray 1, 2 , Kumar Biradha
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2018-01-04 00:00:00 , DOI: 10.1021/acs.cgd.7b01530 Abhijit Garai , Subhrajit Mukherjee , Samit K. Ray 1, 2 , Kumar Biradha
Affiliation
|
An organic salt composed of 4,4′-dinitro-2,2′,6,6′-tetracarboxybiphenyl and acridine has been shown to act as host to accommodate large polyaromatic guest molecules. Carboxylate–pyridinium hydrogen bonds, π–π and cation···π interactions are found to play a pivotal role in these host–guest complexes. All the complexes are found to exhibit distinct colors and photoluminescence which correlate with the charge-transfer interactions between acridinium ion and guest molecules, and ionization potential or donor ability of the guest molecules.
中文翻译：
通过4,4'-Dinitro-2,2'，6,6'-四羧基联苯和A啶组成的有机盐中的芳香客体包含物调节发射特性
由4,4'-二硝基-2,2'，6,6'-四羧基联苯和a啶组成的有机盐已显示出可作为容纳大型聚芳族客体分子的主体。发现羧酸盐-吡啶鎓氢键，π-π和阳离子···π相互作用在这些宿主-客体复合物中起关键作用。发现所有复合物均表现出不同的颜色和光致发光，其与a啶离子和客体分子之间的电荷转移相互作用以及客体分子的电离势或供体能力相关。
更新日期：2018-01-04
中文翻译：
通过4,4'-Dinitro-2,2'，6,6'-四羧基联苯和A啶组成的有机盐中的芳香客体包含物调节发射特性
由4,4'-二硝基-2,2'，6,6'-四羧基联苯和a啶组成的有机盐已显示出可作为容纳大型聚芳族客体分子的主体。发现羧酸盐-吡啶鎓氢键，π-π和阳离子···π相互作用在这些宿主-客体复合物中起关键作用。发现所有复合物均表现出不同的颜色和光致发光，其与a啶离子和客体分子之间的电荷转移相互作用以及客体分子的电离势或供体能力相关。
京公网安备 11010802027423号