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Nickel-Catalyzed Reductive Etherification of Aldehydes at Room Temperature: C–O vs C–C Bond Formation
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1021/acs.joc.7b02281 Sajjad Rahimi 1 , Farhad Panahi 1, 2 , Marzieh Bahmani 1 , Nasser Iranpoor 1
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1021/acs.joc.7b02281 Sajjad Rahimi 1 , Farhad Panahi 1, 2 , Marzieh Bahmani 1 , Nasser Iranpoor 1
Affiliation
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The reaction of secondary and tertiary benzyl alcohols activated by 2,4,6-trichloro-1,3,5-triazine (TCT) with aldehydes in the presence of NiCl2·dmg as a precatalyst in ethylene glycol afforded ethers at room temperature. A selective C–O vs C–C bond formation was observed for the secondary and tertiary benzyl alcohols in comparison with primary ones.
中文翻译：
镍在室温下催化醛的还原醚化：C–O与CC键的形成
在乙二醇中作为前催化剂的NiCl 2 ·dmg存在下，由2,4,6-三氯-1,3,5-三嗪（TCT）活化的仲和叔苄醇与醛的反应在室温下提供了醚。与伯醇相比，仲和叔苄醇具有选择性的C–O和C–C键形成。
更新日期：2018-01-08
中文翻译：
镍在室温下催化醛的还原醚化：C–O与CC键的形成
在乙二醇中作为前催化剂的NiCl 2 ·dmg存在下，由2,4,6-三氯-1,3,5-三嗪（TCT）活化的仲和叔苄醇与醛的反应在室温下提供了醚。与伯醇相比，仲和叔苄醇具有选择性的C–O和C–C键形成。
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