Template-Directed Photochemical [2 + 2] Cycloaddition in Crystalline Materials: A Useful Tool to Access Cyclobutane Derivatives,Crystal Growth & Design

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Template-Directed Photochemical [2 + 2] Cycloaddition in Crystalline Materials: A Useful Tool to Access Cyclobutane Derivatives
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2018-01-17 00:00:00 , DOI: 10.1021/acs.cgd.7b01308
Ming-Ming Gan ₁ , Jian-Gang Yu _{1,

2} , Yao-Yu Wang ₁ , Ying-Feng Han ₁

Affiliation

The photochemical [2 + 2] cycloaddition reaction in crystalline materials is one of most important routes for the synthesis of cyclobutane compounds, which are otherwise difficult to prepare by conventional organic synthesis. In this perspective, a series of olefins that undergo photochemical [2 + 2] cycloaddition reactions is summarized and categorized according to their various functionality. Using these olefins, a range of cyclobutane derivatives were prepared by this [2 + 2] cycloaddition protocol.

中文翻译：

结晶材料中的模板导向光化学[2 + 2]环加成：获得环丁烷衍生物的有用工具

晶体材料中的光化学[2 + 2]环加成反应是合成环丁烷化合物的最重要途径之一，否则这些环丁烷化合物很难通过常规的有机合成方法制备。从这个角度出发，对一系列经历光化学[2 + 2]环加成反应的烯烃进行了总结，并根据其各种功能进行了分类。使用这些烯烃，可通过此[2 + 2]环加成方案制备一系列环丁烷衍生物。

更新日期：2018-01-17

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