Emergence of Surface‐ and Interface‐Induced Structures and Properties in Metal–Organic Framework Thin Films,European Journal of Inorganic Chemistry

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Emergence of Surface‐ and Interface‐Induced Structures and Properties in Metal–Organic Framework Thin Films
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2018-02-20 , DOI: 10.1002/ejic.201701234
Tomoyuki Haraguchi ₁ , Kazuya Otsubo ₂ , Hiroshi Kitagawa _{2,

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Affiliation

Metal–organic frameworks (MOFs) are of particular interest to researchers because of their structural diversity and variety of properties. MOF thin films have been intensively investigated for potential applications such as membranes, gas sensors, catalysts, etc. Although most MOF thin films have almost the same structure and properties as their bulk, some MOF thin films show remarkable structural changes and hidden properties that are not observed in the bulk. These phenomena would be induced by the surface and the interface. Recent improvements in thin‐film fabrication methods enabled us to construct MOF thin films and discuss the properties based on the structure, thickness and crystalline orientation in detail. This microreview describes and discusses the fascinating nature of MOF thin films originating from surface/interface. This paper is expected to help with the construction of a research strategy for MOF thin films to obtain hidden structures and properties of MOFs that are not observed in their bulk.

中文翻译：

金属有机骨架薄膜中表面和界面诱导结构和性能的出现

金属有机框架（MOF）由于其结构的多样性和特性的多样性而引起研究人员的特别兴趣。已对MOF薄膜进行了广泛的研究，以研究其潜在的应用，例如膜，气体传感器，催化剂等。尽管大多数MOF薄膜的结构和性质与其体积几乎相同，但某些MOF薄膜仍显示出显着的结构变化和隐藏特性。散装中未观察到。这些现象将由表面和界面引起。薄膜制造方法的最新改进使我们能够构建MOF薄膜，并根据结构，厚度和晶体取向详细讨论其性能。这篇微型评论描述并讨论了源自表面/界面的MOF薄膜的迷人性质。

更新日期：2018-02-20

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