The Pd‐catalyzed, Cu^I−carboxylate‐mediated cross‐coupling reaction of organosulfur compounds with nucleophilic organometallic reagents is known as the Liebeskind–Srogl cross‐coupling reaction. Owing to the readily available starting materials and neutral reaction conditions, it has become an attractive procedure for the formation of carbon−carbon bonds, in particular for cases in which traditional methods had failed. Since the seminal work of Liebeskind and Srogl in 2000, this reaction has received intense attention from the synthetic community. In this Focus Review, we highlight recent advances in this intriguing cross‐coupling reaction and its applications in organic synthesis.

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Liebeskind-Srogl交叉偶联反应及其合成应用

Pd催化的，Cu ^I-羧酸盐介导的有机硫化合物与亲核有机金属试剂的交叉偶联反应被称为Liebeskind-Srogl交叉偶联反应。由于容易获得的起始原料和中性反应条件，它已成为形成碳-碳键的有吸引力的方法，特别是对于传统方法失败的情况。自2000年Liebeskind和Srogl的开创性工作以来，这一反应受到了合成社区的强烈关注。在本《聚焦评论》中，我们重点介绍了这种有趣的交叉偶联反应及其在有机合成中的应用的最新进展。