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PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic”
Nano Energy ( IF 16.8 ) Pub Date : 2017-12-24 , DOI: 10.1016/j.nanoen.2017.12.037
Long Chen , Yutao Li , Shuai-Peng Li , Li-Zhen Fan , Ce-Wen Nan , John B. Goodenough

Composite polyethylene-oxide/garnet electrolytes containing LiTFSI as the lithium salt have a Li+ conductivity σLi > 10−4 S cm−1 at 55 °C and a low plating/stripping impedance of a dendrite-free Li-metal anode; they have been developed for a safe solid-state Li-metal rechargeable battery. Composites consisting of “ceramic-in-polymer” to “polymer-in-ceramic” that are flexible and mechanically robust are fabricated by hot-pressing. Safe pouch cells with a remarkable flexibility have been fabricated. Solid-state LiFePO4|Li batteries with electrolytes of “ceramic-in-polymer” and “polymer-in-ceramic” deliver excellent cycling stability with high discharge capacities (139.1 mAh g–1 with capacity retention of 93.6% after 100 cycles) and high capacity retention (103.6% with coulombic efficiency of 100% after 50 cycles) at 0.2 C and 55 °C. Both kinds of electrolytes can be applied to solid-state lithium batteries.



中文翻译:

固态锂电池用PEO /石榴石复合电解质:从“陶瓷聚合物”到“陶瓷聚合物”

含有的LiTFSI作为锂盐的复合聚环氧乙烷/石榴石电解质具有锂+电导率σ> 10 -4 小号厘米-1在55℃和无枝晶锂金属阳极的低镀层/汽提阻抗; 它们是为安全的固态锂金属可充电电池而开发的。通过热压制造由“陶瓷中的聚合物”到“陶瓷中的聚合物”组成的柔性且机械坚固的复合材料。已经制造出具有显着灵活性的安全袋式电池。固态LiFePO 4 | 带有“陶瓷聚合物”和“陶瓷聚合物”电解质的锂电池具有出色的循环稳定性和高放电容量(139.1 mAh g –1在100 C循环后的容量保持率为93.6%)和在0.2 C和55°C下的高容量保持率(103.6%,在50个循环后的库仑效率为100%)。两种电解质均可应用于固态锂电池。

更新日期:2017-12-24
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