Lithium imide enolates featuring Evans’ chiral oxazolidinone auxiliary were involved in diastereoselective α‐trifluoromethylthiolation with electrophilic SCF₃ donors. Diastereopure products were isolated and converted to enantiopure α‐SCF₃ alcohols without racemisation.

中文翻译：

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手性恶唑烷酮的非对映选择性亲电子三氟甲基硫醇化：获得对映纯α-SCF3醇

具有Evans手性恶唑烷酮助剂的酰亚胺化锂烯醇盐与亲电子SCF ₃供体一起参与非对映选择性α-三氟甲基硫醇化反应。Diastereopure产物分离并转化为对映体纯α-SCF _3个醇无外消旋作用。