Visible-light-induced iminyl radical formation via electron-donor–acceptor complexes: a photocatalyst-free approach to phenanthridines and quinolines†,Organic Chemistry Frontiers

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Visible-light-induced iminyl radical formation via electron-donor–acceptor complexes: a photocatalyst-free approach to phenanthridines and quinolines†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-12-22 00:00:00 , DOI: 10.1039/c7qo00992e
Jingjing Sun _{1,

2,

3,

4,

5} , Yanyan He _{2,

6,

7,

8,

9} , Xiao-De An _{2,

6,

7,

8,

9} , Xu Zhang _{1,

2,

3,

4,

5} , Lei Yu _{1,

2,

3,

4,

5} , Shouyun Yu _{2,

6,

7,

8,

9}

Affiliation

A visible light-induced synthesis of nitrogen-containing arenes from O-2,4-dinitrophenyl oximes has been reported. This photochemical strategy is photocatalyst-free and enabled by electron-donor–acceptor (EDA) complexes of O-2,4-dinitrophenyl oximes and Et₃N. A variety of highly functionalized nitrogen-containing arenes, including 15 phenanthridines and 8 quinolines, were synthesized in excellent yields.

中文翻译：

通过电子给体-受体配合物形成可见光诱导的亚氨基基团：无光催化剂的菲啶和喹啉†

已经报道了由O -2，4-二硝基苯基肟可见光诱导的含氮芳烃的合成。这种光化学策略是无光催化剂的，并且可以通过O -2,4-二硝基苯基肟和Et ₃ N的电子供体-受体（EDA）络合物来实现。各种高度官能化的含氮芳烃，包括15种菲啶和8种喹啉，以优异的产率合成。

更新日期：2017-12-22

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