Rhodium(iii)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation†,Organic Chemistry Frontiers

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Rhodium(iii)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-12-22 00:00:00 , DOI: 10.1039/c7qo01033h
Guangfan Zheng _{1,

2,

3,

4} , Miaomiao Tian _{4,

5,

6,

7} , Youwei Xu _{1,

2,

3,

4} , Xiaohong Chen _{1,

2,

3,

4} , Xingwei Li _{1,

2,

3,

4,

5}

Affiliation

The Rh(III)-catalyzed annulative C–H functionalization of arenes with sulfoxonium ylides has been realized. Arenes assisted by diverse nucleophilic directing groups are viable substrates, and the coupling affords structurally diverse fused hetero- and carbocycles under redox-neutral conditions.

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