Synthetic membranes play an increasingly critical role in various energy and environment-related applications such as carbon capture and water purification. Owing to the great promise in solving the permeability/selectivity trade-off and the separation performance/stability trade-off, heterogeneous membranes primarily including mixed matrix membranes and composite membranes have become a prevalent membrane configuration in various membrane processes. For heterogeneous membranes, interfacial interaction is an essential factor, which governs the nano-/molecular-scale assembly of membrane materials, tunes the hierarchical structures and enhances the comprehensive properties of membranes. This review highlights the recent advances in manipulating interfacial interactions of heterogeneous membranes with the focus on two kinds of typical interfaces: the separation layer-support layer interface in composite membranes and the polymer matrix-filler interface in mixed matrix membranes. Common methods for interfacial interactions manipulation of heterogeneous membranes are extensively summarized. The applications of manipulating interactions at membrane interfaces in energy and environment-related realms are briefly introduced. Finally, the future directions of manipulating interfacial interactions of heterogeneous membranes are tentatively identified.

合成膜在各种与能源和环境相关的应用（例如碳捕获和水净化）中扮演着越来越重要的角色。由于在解决渗透率/选择性的权衡和分离性能/稳定性的权衡方面有很大的希望，主要包括混合基质膜和复合膜的非均质膜已成为各种膜工艺中普遍的膜构型。对于异质膜，界面相互作用是一个至关重要的因素，它控制着膜材料的纳米/分子级组装，调整了层次结构并增强了膜的综合性能。这篇综述着重介绍了操纵异质膜界面相互作用的最新进展，重点是两种典型的界面：复合膜中的分离层-支撑层界面和混合基质膜中的聚合物基质-填料界面。广泛概述了异质膜界面相互作用的常用方法。简要介绍了操纵膜界面在能量和环境相关领域中的相互作用的应用。最后，初步确定了操纵异质膜界面相互作用的未来方向。简要介绍了操纵膜界面在能量和环境相关领域中的相互作用的应用。最后，初步确定了操纵异质膜界面相互作用的未来方向。简要介绍了操纵膜界面在能量和环境相关领域中的相互作用的应用。最后，初步确定了操纵异质膜界面相互作用的未来方向。