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Mild‐Base‐Promoted Arylation of (Hetero)Arenes with Anilines
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2018-01-10 , DOI: 10.1002/asia.201701585
Diego M. Monzón 1 , Tanausú Santos 1 , F. Pinacho-Crisóstomo 1 , Víctor S. Martín 1 , Romen Carrillo 1, 2
Affiliation  

Transition metal‐free radical arylation of heteroarenes is achieved at room temperature by simply adding aqueous sodium carbonate to a solution of the corresponding heteroarene and arenediazonium salt, which can even be formed in situ. Such an easy, inexpensive and mild methodology has been optimized and applied to the expeditious modification of interesting molecular cores like naphthylimide or bisthienylcyclopentenes.

中文翻译:

(杂)戊烯与苯胺的温和碱促进的芳构化

杂芳烃的过渡金属自由基芳基化是在室温下完成的,方法是将碳酸钠水溶液简单地添加到相应的杂芳烃和二氮杂salt鎓盐的溶液中,甚至可以原位形成。这种简便,廉价和温和的方法已得到优化,并已用于快速修饰有趣的分子核,如萘甲酰亚胺或联苯二环环戊烯。
更新日期:2018-01-10
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