当前位置: X-MOL 学术Chem. Phys. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Hydrogen Peroxide Vapor Cross Sections: A Flow Cell Study Using Laser Absorption in the Near Infrared
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2017-12-20 , DOI: 10.1016/j.cplett.2017.12.053
B.L. Rhodes , P.D. Ronney , J.D. DeSain

The absorption spectra of vapors of concentrated hydrogen peroxide / water mixtures (without a carrier gas) were characterized at wavelengths from 1390 to 1470 nm utilizing a near-infrared diode laser. Low pressures were employed to examine these spectral features near the Doppler-broadened limit. An advantageous portion of the spectra near 1420 nm containing several distinct H2O2 peaks and one well-known H2O peak (for calibration) was identified and the cross-sections of these peaks determined. These cross section values can be employed to measure vapor-phase concentrations of H2O2 in propulsion, atmospheric chemistry, and sterilization applications.



中文翻译:

过氧化氢蒸气横截面:使用近红外激光吸收的流式细胞研究

使用近红外二极管激光器在1390至1470 nm的波长处表征了浓过氧化氢/水混合物(无载气)的蒸气的吸收光谱。低压被用来检查这些频谱特征在多普勒展宽的极限附近。在1420nm附近的光谱的有利部分被确定,该光谱包含几个不同的H 2 O 2峰和一个众所周知的H 2 O峰(用于校准),并确定这些峰的横截面。这些横截面值可用于测量推进,大气化学和灭菌应用中H 2 O 2的气相浓度。

更新日期:2017-12-21
down
wechat
bug