Front Cover: Intramolecular Hydroamination by a Primary Amine of an Unactivated Alkene on Gold Nanoclusters: A DFT Study (ChemCatChem 24/2017),ChemCatChem

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Front Cover: Intramolecular Hydroamination by a Primary Amine of an Unactivated Alkene on Gold Nanoclusters: A DFT Study (ChemCatChem 24/2017)
ChemCatChem ( IF 3.8 ) Pub Date : 2017-12-20 , DOI: 10.1002/cctc.201701911
Karan Bobuatong _{1,

2,

3} , Hidehiro Sakurai ₄ , Masahiro Ehara _{1,

2}

Affiliation

The Front Cover shows that the intramolecular hydroamination of an unactivated alkene by a primary amine follows an anti‐addition mechanism if a colloidal gold nanocluster (NC) is used as catalyst. In their Full Paper, K. Bobuatong et al. used DFT calculations to demonstrate how O₂ activation, the Lewis acid character of Au NCs, and the presence of hydrated formic acid are relevant to the reaction pathways that this transformation can follow. More information can be found in the Full Paper by K. Bobuatong et al. on page 4490 in Issue 24, 2017 (DOI: 10.1002/cctc.201700839).

中文翻译：

封面：金纳米簇上未活化烯烃的伯胺进行的分子内加氢胺化：DFT研究（ChemCatChem 24/2017）

封面显示，如果使用胶体金纳米团簇（NC）作为催化剂，伯胺对未活化烯烃进行分子内加氢胺化反应具有抗加成机理。在他们的论文全文中，K。Bobuatong等人。使用DFT计算来证明O ₂活化，Au NCs的Lewis酸特征以及水合甲酸的存在与该转化可以遵循的反应途径有关。可以在K. Bobuatong等人的论文全文中找到更多信息。就在第24期，2017年4490页（：10.1002 / cctc.201700839 DOI）。

更新日期：2017-12-20

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