A BN Aromatic Ring Strategy for Tunable Hydroxy Content in Polystyrene,Angewandte Chemie International Edition

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A BN Aromatic Ring Strategy for Tunable Hydroxy Content in Polystyrene
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-01-16 , DOI: 10.1002/anie.201711650
Heidi L. van de Wouw ₁ , Jae Young Lee ₁ , Elorm C. Awuyah ₁ , Rebekka S. Klausen ₁

Affiliation

BN 2‐vinylnaphthalene, a BN aromatic vinyl monomer, is copolymerized with styrene under free radical conditions. Oxidation yields styrene–vinyl alcohol (SVA) statistical copolymers with tunable hydroxy group content. Comprehensive spectroscopic investigation provides proof of structure. Physical properties that vary systematically with hydroxy content include solubility and glass transition temperature. BN aromatic polymers represent a platform for the preparation of diverse functional polymeric architectures via the remarkable reaction chemistry of C−B bonds.

中文翻译：

BN芳香环策略可调节聚苯乙烯中的羟基含量

BN 2-乙烯基萘（一种BN芳香族乙烯基单体）在自由基条件下与苯乙烯共聚。氧化生成具有可调羟基含量的苯乙烯-乙烯醇（SVA）统计共聚物。全面的光谱研究提供了结构证明。随羟基含量而系统变化的物理性质包括溶解度和玻璃化转变温度。BN芳族聚合物代表了通过功能强大的C-B键反应化学制备各种功能性聚合物结构的平台。

更新日期：2018-01-16

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