A M18L6 metal–organic nanocapsule with open windows using mixed macrocycles,Chemical Communications

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A M18L6 metal–organic nanocapsule with open windows using mixed macrocycles
Chemical Communications ( IF 4.3 ) Pub Date : 2017-12-19 00:00:00 , DOI: 10.1039/c7cc09294f
Chen Zhang _{1,

2,

3} , Kanishka Sikligar _{1,

2,

3} , Rahul S. Patil _{1,

2,

3} , Charles L. Barnes _{1,

2,

3} , Gary A. Baker _{1,

2,

3} , Jerry L. Atwood _{1,

2,

3}

Affiliation

We present here the preparation of a M₁₈L₆ hexameric metal–organic nanocapsule using a pyrogallol[3]resorcin[1]arene mixed macrocycle. The introduction of resorcinol moieties within the assembly leads to the formation of two open windows. This study demonstrates that introducing defects into the existing structure of nanocapsules may act as an effective method to tailor the composition and geometry, and introduce new properties.

中文翻译：

AM ₁₈ L ₆金属-有机纳米胶囊，具有使用混合大环化合物的开窗

我们在这里介绍使用邻苯三酚[3]间苯二酚[1]芳烃混合大环化合物制备M ₁₈ L ₆六聚金属有机纳米胶囊。组件中引入间苯二酚部分导致形成两个打开的窗口。这项研究表明，在现有的纳米胶囊结构中引入缺陷可能是一种有效的方法，可以调整其组成和几何形状，并引入新的特性。

更新日期：2018-01-16

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