当前位置: X-MOL 学术Chem. Commun. › 论文详情
Aromaticity switching via azulene transformations in azulene-bridged A,D-dithiahexaphyrin
Chemical Communications ( IF 6.319 ) Pub Date : 2017-12-19 , DOI: 10.1039/C7CC08754C
Michał J. Białek, Lechosław Latos-Grażyński

The incorporation of an azulene bridge into an aromatic hexaphyrin framework allows manipulating π-electron delocalization pathways. The palladium(II) complex undergoes hydroxyl-triggered azulene contraction or isomerization to an oxynaphthalene unit, transforming the hexaphyrin framework into meso-linked carbaporphyrins. This converts the 26π-electron pathway into the 18π one.
更新日期:2018-01-03

 

Some contents have been Reproduced with permission of the American Chemical Society.
Some contents have been Reproduced by permission of The Royal Society of Chemistry.
分享到
评论: 0
期刊列表
Wiley论文编辑服务,每月大奖送不停!
深圳大学-同济大学联合招聘博士后(税后年薪30万)
华中师范大学第一届国际青年学者化学科学论坛
【问答】大分子介晶有哪些重要意义?
X-MOL近期新增451种期刊(20171216)
2017年中科院JCR分区化学大类列表
试剂库存管理
化合物查询
down
wechat
bug