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Aromaticity switching via azulene transformations in azulene-bridged A,D-dithiahexaphyrin
Chemical Communications ( IF 6.319 ) Pub Date : 2017-12-19 , DOI: 10.1039/C7CC08754C
Michał J. Białek, Lechosław Latos-Grażyński

The incorporation of an azulene bridge into an aromatic hexaphyrin framework allows manipulating π-electron delocalization pathways. The palladium(II) complex undergoes hydroxyl-triggered azulene contraction or isomerization to an oxynaphthalene unit, transforming the hexaphyrin framework into meso-linked carbaporphyrins. This converts the 26π-electron pathway into the 18π one.
更新日期:2018-02-15

 

Some contents have been Reproduced with permission of the American Chemical Society.
Some contents have been Reproduced by permission of The Royal Society of Chemistry.
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