Lewis Pair-Mediated Surface-Initiated Polymerization,ACS Macro Letters

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Lewis Pair-Mediated Surface-Initiated Polymerization
ACS Macro Letters ( IF 5.1 ) Pub Date : 2017-12-19 00:00:00 , DOI: 10.1021/acsmacrolett.7b00903
Liman Hou _{1,

2} , Yongjiu Liang ₁ , Qianyi Wang ₃ , Yuetao Zhang ₃ , Dewen Dong ₁ , Ning Zhang ₁

Affiliation

We present the first example of surface-initiated polymerization mediated by Lewis pairs for the synthesis of polymer brushes on planar substrates. The method enables the rapid grafting polymerization from the self-assembled monolayer or surface-attached macroinitiators, furnishing linear polymer brushes and bottle-brush brushes. Both homopolyester and block copolyester brushes can be synthesized via this versatile approach. This work not only opens up new opportunities for the application of Lewis pair-mediated polymerization but also enriches the surface-initiated polymerization on different surfaces.

中文翻译：

路易斯对介导的表面引发聚合

我们提出了由路易斯对介导的表面引发聚合的第一个例子，用于在平面基板上合成聚合物刷。该方法能够从自组装单层或表面附着的大分子引发剂进行快速接枝聚合，提供线性聚合物刷和瓶刷刷。均聚酯和嵌段共聚酯刷都可以通过这种通用方法合成。这项工作不仅为路易斯对介导聚合的应用开辟了新的机遇，而且丰富了不同表面上的表面引发聚合。

更新日期：2017-12-19

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