In this study, under a sonochemical method, a 3D, porous Zn(II)-based metal-organic framework [Zn(TDC)(4-BPMH)]_n·n(H₂O) is produced, which is called compound 1. To this end, the dicarboxylate linker of TDC, (2,5-thiophene dicarboxylic acid) and the pillar spacer of 4-BPMH, (N,N-bis-pyridin-4-ylmethylene-hydrazine) were employed. Moreover, variations in the morphology and growth of the micro/nanoparticles of compound 1 were investigated in terms of the effect of temperature, ultrasound irradiation power, sonication time, initial reagent concentrations, and pyridine concentration as a modulator. DFT model was used to examine the sonication effect on the distribution of the pore sizes. Moreover, the preparation method effect on the porosity and removal of two sample pollutants (i.e., 2,4-dichlorophenol (24-DCP) and amoxicillin (AMX)) from wastewater was studied.

在这项研究中，通过声化学方法，一种3D多孔Zn（II）基金属有机骨架[Zn（TDC）（4-BPMH）] _n ·n（H _2）产生O），称为化合物1。为此，TDC的二羧酸酯连接基（2,5-噻吩二羧酸）和4-BPMH的柱间隔基（N，N-双-吡啶-4-使用亚甲基-肼）。此外，根据温度，超声辐射功率，超声处理时间，初始试剂浓度和作为调节剂的吡啶浓度的影响，研究了化合物1的微米/纳米颗粒的形态和生长的变化。使用DFT模型检查超声处理对孔径分布的影响。此外，研究了制备方法对废水中两种样品污染物（即2,4-二氯苯酚（24-DCP）和阿莫西林（AMX））的孔隙率和去除的影响。