Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers via ROMP†,Polymer Chemistry

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Oxadiazabicyclooctenone as a versatile monomer for the construction of pH sensitive functional polymers via ROMP†
Polymer Chemistry ( IF 4.1 ) Pub Date : 2017-12-18 00:00:00 , DOI: 10.1039/c7py01413a
Asadulla Mallick _{1,

2,

3,

4} , Yuan Xu _{1,

2,

3,

4} , Yichao Lin _{1,

2,

3,

4} , Jingxi He _{5,

6,

7,

8} , Mary B. Chan-Park _{5,

6,

7,

8} , Xue-Wei Liu _{1,

2,

3,

4,

5}

Affiliation

Ring-opening metathesis polymerization (ROMP) is a powerful method for the synthesis of various functional polymers including, but not limited to, biologically active polymers owing to its living character. However, the majority of polymers obtained by ROMP have a nondegradable backbone and there are very few examples of fully degradable polymers synthesized via ROMP. Herein, oxadiazabicyclooctenone is successfully developed as a versatile monomer for the construction of new pH-sensitive polymers by ROMP. The degradability was also introduced into the backbone of poly(oxa)norbornenes by copolymerization.

中文翻译：

恶二氮杂双环辛烯酮作为通用单体，可通过ROMP †构建pH敏感的功能聚合物

开环复分解聚合（ROMP）是一种强大的方法，用于合成各种功能性聚合物，由于其活性特性，这些功能性聚合物包括但不限于生物活性聚合物。然而，通过ROMP获得的大多数聚合物具有不可降解的主链，并且很少有通过ROMP合成的完全可降解的聚合物的例子。本文中，恶二氮杂双环辛烯酮已成功开发为用于通过ROMP构造新的pH敏感聚合物的通用单体。还通过共聚将可降解性引入到聚（氧杂）降冰片烯的主链中。

更新日期：2017-12-18

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