Halogen-Bonded Cocrystals as Optical Materials: Next-Generation Control over Light–Matter Interactions,Crystal Growth & Design

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Halogen-Bonded Cocrystals as Optical Materials: Next-Generation Control over Light–Matter Interactions
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1021/acs.cgd.7b01445
J.-C. Christopherson ₁ , F. Topić ₁ , C. J. Barrett ₁ , T. Friščić ₁

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This review summarizes the recent advances in utilizing halogen bond-driven cocrystal formation as a design element in the creation of optical or photoresponsive materials, notably cocrystals and liquid crystals. The extensive work over a relatively short time has demonstrated halogen bonding as a versatile supramolecular interaction capable of creating libraries of fluorescent, phosphorescent, dichroic, photoswitchable, as well as photomechanical crystals and liquid crystals. Such rapid development, and the diversity of materials properties that have been designed or fine-tuned with success, signal the emergence of halogen-bonded cocrystallization as an exciting new playground for crystal engineers, chemists, and physicists to develop next-generation optical materials.

中文翻译：

卤素键合共晶体作为光学材料：光物质相互作用的下一代控制

这篇综述总结了利用卤素键驱动的共晶体形成作为光学或光响应材料（特别是共晶体和液晶）的设计元素的最新进展。在相对较短的时间内进行的大量工作表明，卤素键是一种通用的超分子相互作用，能够形成荧光，磷光，二向色，可光转换以及光机械晶体和液晶的库。如此迅速的发展以及已成功设计或微调的材料特性的多样性，预示着卤素键合共结晶的出现，成为晶体工程师，化学家和物理学家开发下一代光学材料的令人兴奋的新游乐场。

更新日期：2018-01-08

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