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Substituted Hantzsch Esters as Versatile Radical Reservoirs in Photoredox Reactions
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2017-12-29 , DOI: 10.1002/adsc.201701348
Fangjun Gu 1 , Wenhao Huang 1 , Xu Liu 1 , Wenxin Chen 1 , Xu Cheng 1, 2
Affiliation  

Substituted Hantzsch esters can act as radical reservoirs in photoredox reactions, steadily releasing a carbon radical and a hydrogen atom radical in the absence of an additional electron acceptor. We propose that radical release by substituted Hantzsch esters occurs via a mechanism involving an internal redox cycle. Cinnamidecinnamides, styrenes, α,β‐unsaturated acids, and diarylethenes could be alkylated smoothly with these reagents.

中文翻译:

取代Hantzsch酯作为光氧化还原反应中的多用途自由基贮库

取代的Hantzsch酯可在光氧化还原反应中充当自由基储存库,在不存在其他电子受体的情况下稳定释放碳自由基和氢原子自由基。我们建议,通过涉及内部氧化还原循环的机制,发生由取代的汉茨(Hantschsch)酯释放的自由基。肉桂酰胺,苯乙烯,α,β-不饱和酸和二芳烃可以用这些试剂平稳地烷基化。
更新日期:2017-12-29
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