Synthesis ( IF 2.2 ) Pub Date : 2017-12-14 , DOI: 10.1055/s-0036-1589155 Xiaodong Jia 1, 2 , Pengfei Li 1
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Abstract
tert-Butyl nitrite (TBN) is an important metal-free reagent that is widely applied in various organic transformations. Besides its traditional applications in nitrosation and diazotization, its ability to activate molecular oxygen to enable the initiation of radical reactions, including nitration, oximation, oxidation, and so on, has attracted extensively attention in the past decade. This review highlights recent advances in this field to promote further exploration of this versatile compound.
1 Introduction
2 Reactions Involving TBN
2.1 Nitrosation
2.2 Oximation
2.3 Diazotization
2.4 Nitration
2.5 Oxidation
2.6 Other Reactions
3 Conclusion and Perspective
tert-Butyl nitrite (TBN) is an important metal-free reagent that is widely applied in various organic transformations. Besides its traditional applications in nitrosation and diazotization, its ability to activate molecular oxygen to enable the initiation of radical reactions, including nitration, oximation, oxidation, and so on, has attracted extensively attention in the past decade. This review highlights recent advances in this field to promote further exploration of this versatile compound.
1 Introduction
2 Reactions Involving TBN
2.1 Nitrosation
2.2 Oximation
2.3 Diazotization
2.4 Nitration
2.5 Oxidation
2.6 Other Reactions
3 Conclusion and Perspective
中文翻译：
亚硝酸叔丁酯（TBN）作为有机合成中的多功能试剂
摘要
亚硝酸叔丁酯（TBN）是一种重要的无金属试剂，已广泛应用于各种有机转化中。除了在亚硝化和重氮化中的传统应用外，其活化分子氧以启动自由基反应（包括硝化，肟化，氧化等）的能力在过去十年中引起了广泛关注。这篇综述重点介绍了该领域的最新进展，以促进对该多功能化合物的进一步探索。
1引言
2涉及TBN的反应
2.1亚硝化
2.2氧化
2.3重氮化
2.4硝化
2.5氧化
2.6其他反应
3结论与展望
亚硝酸叔丁酯（TBN）是一种重要的无金属试剂，已广泛应用于各种有机转化中。除了在亚硝化和重氮化中的传统应用外，其活化分子氧以启动自由基反应（包括硝化，肟化，氧化等）的能力在过去十年中引起了广泛关注。这篇综述重点介绍了该领域的最新进展，以促进对该多功能化合物的进一步探索。
1引言
2涉及TBN的反应
2.1亚硝化
2.2氧化
2.3重氮化
2.4硝化
2.5氧化
2.6其他反应
3结论与展望
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