Hybrid composites of MIL-101(Cr) and graphene oxide (GrO) were prepared using a hydrothermal synthesis method. The synthesized materials were characterized using scanning electron microscopy, X-ray diffraction, FT-IR spectroscopy, thermal analysis and nitrogen adsorption. Results indicated that the specific area and pore volume of MIL-101/GrO-0.25 was much higher than pure MIL-101, and the adsorption capacities of carbon tetrachloride on the MIL-101 (Cr)/GrO was also higher than MIL-101. Moreover, the Langmuir-Freundlich (L-F) equation gave a well fit to the adsorption isotherm data of carbon tetrachloride. The result showed that the adsorption capacity of carbon tetrachloride on the MIL-101 at 303 K was 2044.4 mg/g, and the adsorbing amount on the MIL-101/GrO-0.25 was up to 2368.1 mg/g, which increased by 16% in comparison with the original MIL-101. The synthesized MIL-101/GrO composites exhibited a higher carbon tetrachloride uptake capacity than normal MIL-101 owing to the increasing of specific area, dispersion forces and defects on the crystal surface. Furthermore, the carbon tetrachloride uptakes of MIL-101 and MIL-101/GrO composites were well above those of conventional adsorbents, such as activated carbons and zeolites. It was demonstrated that the MIL-101 and MIL-101/GrO composite are promising adsorbents for application in the field of chlorinated volatile organic compounds (Cl-VOCs) adsorption.

采用水热合成法制备了MIL-101（Cr）和氧化石墨烯（GrO）的杂化复合材料。使用扫描电子显微镜，X射线衍射，FT-IR光谱，热分析和氮吸附对合成的材料进行表征。结果表明，MIL-101 / GrO-0.25的比表面积和孔容远高于纯MIL-101，四氯化碳在MIL-101（Cr）/ GrO上的吸附容量也高于MIL-101 。此外，Langmuir-Freundlich（LF）方程与四氯化碳的吸附等温线数据非常吻合。结果表明，303 K下四氯化碳在MIL-101上的吸附容量为2044.4 mg / g，在MIL-101 / GrO-0.25上的吸附量高达2368.1 mg / g，与原始的MIL-101相比增加了16％。由于比表面积，分散力和晶体表面缺陷的增加，合成的MIL-101 / GrO复合材料比普通的MIL-101表现出更高的四氯化碳吸收能力。此外，MIL-101和MIL-101 / GrO复合材料的四氯化碳吸收量远高于传统吸附剂（如活性炭和沸石）的四氯化碳吸收量。结果表明，MIL-101和MIL-101 / GrO复合材料是有希望的吸附剂，可用于氯化挥发性有机化合物（Cl-VOCs）吸附领域。MIL-101和MIL-101 / GrO复合材料的四氯化碳吸收量远高于传统吸附剂（如活性炭和沸石）的四氯化碳吸收量。结果表明，MIL-101和MIL-101 / GrO复合材料是有希望的吸附剂，可用于氯化挥发性有机化合物（Cl-VOCs）吸附领域。MIL-101和MIL-101 / GrO复合材料的四氯化碳吸收量远高于传统吸附剂（如活性炭和沸石）的四氯化碳吸收量。结果表明，MIL-101和MIL-101 / GrO复合材料是有希望的吸附剂，可用于氯化挥发性有机化合物（Cl-VOCs）吸附领域。