The development of the nonaqueous Li–O₂ battery, a promising candidate for high‐gravimetric‐energy‐storage techniques, is seriously restrained by the high charge overpotential during electrochemical decomposition of insulating Li₂O₂. Benefiting from the photovoltage, photo‐assisted charging is revealed as a feasible method to reduce the charge potential. However, a long period of illumination will inevitably aggravate the degradation of the electrolyte. Herein, composed of contact‐ion‐pairs (CIPs), a newly introduced superconcentrated electrolyte presents superior stability against parasitic photocatalytic decomposition. More significantly, the conventional and photo‐assisted charging processes are rationally integrated as a unique hybrid strategy, in which the highly polarized charging stage is replaced by the photo‐assisted Li₂O₂‐scavenging process. By tuning the photocatalysis and Li₂O₂ electrochemical oxidization, the hybrid Li₂O₂‐scavenging strategy not only boosts the cycle life of rechargeable Li–O₂ batteries but also opens possibilities in designing photocatalysis‐involved rechargeable energy‐storage battery systems.

中文翻译：

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通过光辅助混合Li2O2清除策略来延长非质子Li-O2电池的循环寿命

非水Li–O ₂电池的发展，它是高重力能量存储技术的有希望的候选者，但由于绝缘Li ₂ O _2的电化学分解过程中的高电荷超电势而受到严重限制。受益于光电压，光辅助充电被认为是降低充电电位的一种可行方法。然而，长时间的照明将不可避免地加剧电解质的降解。在此，由接触离子对（CIP）组成的新引入的超浓缩电解质具有出色的抗寄生光催化分解稳定性。更重要的是，常规和光辅助充电过程被合理地整合为一种独特的混合策略，其中高极化充电阶段被光辅助Li ₂ O ₂清除过程所取代。通过调节光催化作用和Li ₂ O _2的电化学氧化，杂化Li ₂ O₂清除策略不仅可以延长可充电Li–O ₂电池的循环寿命，而且为设计涉及光催化的可充电储能电池系统提供了可能性。