Catalysis Communications ( IF 3.4 ) Pub Date : 2017-12-07 , DOI: 10.1016/j.catcom.2017.12.002 Yong-Ming Dai , Ya-Fen Wang , Chiing-Chang Chen
This study is focused on the transesterification of the soybean oil into biodiesel using magnetic based solid catalysts (LiFe5O8-LiFeO2). The catalyst was prepared through a simple solid-state reaction that involved mixing and grinding iron oxide (Fe2O3) and Li2CO3. The results demonstrated that the catalyst was ferromagnetic. Under the optimal reaction conditions, the highest FAME conversion in the transesterification of soybean oil can reach 96.5% by using LiFe5O8-LiFeO2 catalyst. The LiFe5O8-LiFeO2 demonstrates excellent catalytic activities and it could be recovered by magnetic separation. The LiFe5O8-LiFeO2 can be easily recovered and reused without significant deactivation.
中文翻译:
磁性LiFe 5 O 8 -LiFeO 2作为生物柴油生产的固体碱性催化剂的合成与表征
这项研究的重点是使用基于磁性的固体催化剂(LiFe 5 O 8 -LiFeO 2)将大豆油酯交换为生物柴油。通过简单的固态反应制备催化剂,该反应涉及混合和研磨氧化铁(Fe 2 O 3)和Li 2 CO 3。结果表明该催化剂是铁磁性的。在最佳反应条件下,使用LiFe 5 O 8 -LiFeO 2催化剂,大豆油酯交换反应中的最高FAME转化率可达到96.5%。LiFe 5 O 8 -LiFeO 2具有良好的催化活性,可以通过磁分离法回收。LiFe 5 O 8 -LiFeO 2可以容易地回收和再利用而没有明显的失活。