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Measurement and Prediction of Vapor–Liquid Equilibria in Ternary Systems Containing an Organic Component, Cyclohexylamine, and Cyclohexanol
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2017-12-12 00:00:00 , DOI: 10.1021/acs.jced.7b00721
Mandy Klauck 1 , Thomas Hähnel 1 , Sandra Richter 1 , Jürgen Schmelzer 1 , Grit Kalies 1
Affiliation  

The isothermal vapor–liquid equilibrium data are presented for three ternary systems: octane + cyclohexylamine + cyclohexanol, cyclohexane + cyclohexylamine + cyclohexanol, and toluene + cyclohexylamine + cyclohexanol. The experimental data were determined by the dynamic method in a modified Röck and Sieg circulation still at two different temperatures and reduced pressures. The experimental results were compared with the predictions from both UNIQUAC and NRTL activity coefficient models and the equation of state proposed by Elliott, Suresh, and Donohue (ESD EOS).

中文翻译:

包含有机成分,环己胺和环己醇的三元体系中汽液平衡的测量和预测

给出了三个三元系统的等温气液平衡数据:辛烷+环己胺+环己醇,环己烷+环己胺+环己醇和甲苯+环己胺+环己醇。实验数据是通过动态方法在改良的Röck和Sieg循环中仍在两个不同的温度和减压下确定的。将实验结果与UNIQUAC和NRTL活度系数模型的预测以及Elliott,Suresh和Donohue(ESD EOS)提出的状态方程进行了比较。
更新日期:2017-12-12
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