Ethylene/vinyl acetate-based macrocycles via organometallic-mediated radical polymerization and CuAAC ‘click’ reaction†,Polymer Chemistry

当前位置： X-MOL 学术 › Polym. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Ethylene/vinyl acetate-based macrocycles via organometallic-mediated radical polymerization and CuAAC ‘click’ reaction†
Polymer Chemistry ( IF 4.1 ) Pub Date : 2017-12-11 00:00:00 , DOI: 10.1039/c7py01891f
Jérémy Demarteau _{1,

2,

3,

4,

5} , Julien De Winter _{6,

7,

8,

9} , Christophe Detrembleur _{1,

2,

3,

4,

5} , Antoine Debuigne _{1,

2,

3,

4,

5}

Affiliation

Recent advances in organometallic-mediated radical polymerization led to unique α,ω-difunctional poly(vinyl acetate) (PVAc) and ethylene/vinyl acetate copolymers (EVA). A copper-catalyzed Huisgen dipolar cycloaddition ring-closure reaction was applied to these difunctional precursors paving the way to unprecedented PVAc and/or EVA macrocycles, and to their PVOH- and EVOH-counterparts after hydrolysis.

中文翻译：

通过有机金属介导的自由基聚合和CuAAC的“点击”反应，基于乙烯/乙酸乙烯酯的大环化合物†

有机金属介导的自由基聚合的最新进展导致了独特的α，ω-双官能聚乙酸乙烯酯（PVAc）和乙烯/乙酸乙烯酯共聚物（EVA）。将铜催化的惠斯根偶极环加成环闭环反应应用于这些双官能团前体，为史无前例的PVAc和/或EVA大环以及水解后的PVOH和EVOH对应物铺平了道路。

更新日期：2017-12-11

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11