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Thiomolybdate [Mo3S13]2− nanocluster: a molecular mimic of MoS2 active sites for highly efficient photocatalytic hydrogen evolution
Chemical Communications ( IF 4.3 ) Pub Date : 2017-12-12 00:00:00 , DOI: 10.1039/c7cc08178b
Yonggang Lei 1, 2, 3, 4 , Meiqun Yang 1, 2, 3, 4 , Jianhua Hou 1, 2, 3, 4 , Fang Wang 1, 2, 3, 4 , Entian Cui 4, 5, 6, 7 , Chao Kong 4, 8, 9, 10 , Shixiong Min 1, 2, 3, 4
Affiliation  

Thiomolybdate [Mo3S13]2− nanoclusters, as a molecular mimic of MoS2 edge sites, showed high efficiency in catalyzing photochemical H2 evolution from a molecular system of Ru(bpy)3Cl2–ascorbic acid (H2A) under visible light irradiation (≥420 nm), providing a turnover number of 1570 and an initial turnover frequency of 335 h−1 for H2 evolution based on the [Mo3S13]2− catalyst.

中文翻译:

硫钼酸盐[Mo 3 S 13 ] 2-纳米簇:MoS 2活性位的分子模拟,可高效光催化制氢

硫代[沫3小号13 ] 2-纳米簇,作为分子模拟物的MoS 2边缘部位,表现出较高的效率在催化光化学ħ 2选自Ru(联吡啶)的分子系统进化32抗坏血酸(H 2 A)在可见光照射下(≥420nm),基于[Mo 3 S 13 ] 2-的H 2析出提供了1570的转换次数和335 h -1的初始转换频率。
更新日期:2018-01-16
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