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Design and synthesis of wool-like Co-Mg [email protected]4 nanosheet material for high performance supercapacitors
Composites Part A: Applied Science and Manufacturing ( IF 8.7 ) Pub Date : 2017-12-07 , DOI: 10.1016/j.compositesa.2017.12.007
Yu Zhang , Wei-dong Xue , Huan Yin , Dong-xu He , Rui Zhao

We have elaborated nanocomposite electrodes, which were designed and synthesized via facile hydrothermal with further annealing processes of NiMoO4 nanosheets on cobalt and magnesium double hydroxide (DH) growing directly on Ni foam. The integrated electrode (the optimum hydrothermal time 6 h) designed according to this structural pattern, had an excellent electrochemical performance along with a high areal-specific capacitance of 6.50 F cm−2 at 5 mA cm−2 and retained 56% at 60 mA cm−2, the capacitance of the electrode material remained 74% after 5000 cycles at 40 mA cm−2. The Co-Mg [email protected]4 and activated carbon were assembled into an asymmetric supercapacitor (Co-Mg [email protected]4//AC), which allowed the feasible voltage could reach 1.6 V and a high energy density of 57 W h kg−1 at the power density of 0.4 kW kg−1. The Co-Mg [email protected]4//AC also showed significant cyclic stability with the capacitance retention of 87% after 5000 cycles.



中文翻译:

用于高性能超级电容器的羊毛状Co-Mg [受电子邮件保护] 4纳米片材料的设计与合成

我们精心设计了纳米复合电极,该电极是通过便捷的水热法设计和合成的,并在镍上直接生长在镍泡沫上的NiMoO 4纳米片和双氢氧化镁(DH)进行了进一步的退火处理。根据该结构模式设计的集成电极(最佳水热时间为6小时)具有出色的电化学性能,在5 mA cm -2时具有6.50 F cm -2的高面积比电容,在60 mA时保持56%的容量cm -2时,电极材料的电容在40 mA cm -2的条件下经过5000次循环后仍保持74%。Co-Mg [电子邮件保护] 4然后将活性炭和活性炭组装成不对称超级电容器(Co-Mg [受电子邮件保护] 4 // AC),这使可行电压可以达到1.6 V,并且在功率密度为0.4时具有57 W h kg -1的高能量密度千瓦kg -1。Co-Mg [受电子邮件保护] 4 // AC还显示出显着的循环稳定性,在5000次循环后电容保持率为87%。

更新日期:2017-12-07
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