The development of silica‐supported molecular catalysts for tandem reactions is an important research direction of heterogeneous catalysis. Besides their significant merits in sustainable catalytic processes, numerous strategies have been utilized to construct silica‐supported molecular catalysts. Here, we emphasize tandem reactions and summarize the recent advances in sequential organic transformations. This paper is composed of four parts. The beginning part introduces silica as supports. The second part provides a large number of examples for the construction of non‐chiral molecular catalysts used for tandem reactions. The third part offers an outline for the construction of chiral molecular catalysts used for enantioselective tandem reactions. Finally, the perspectives for the further development of silica‐supported molecular catalysts for tandem reactions are addressed.

中文翻译：

---

二氧化硅支持的串联反应分子催化剂

硅胶负载的串联反应分子催化剂的开发是异相催化的重要研究方向。除了在可持续催化过程中的显着优势外，还采用了许多策略来构建二氧化硅负载的分子催化剂。在这里，我们强调串联反应，并总结了顺序有机转化的最新进展。本文由四个部分组成。开始部分介绍二氧化硅作为载体。第二部分提供了大量用于串联反应的非手性分子催化剂的构建实例。第三部分概述了用于对映选择性串联反应的手性分子催化剂的结构。最后，