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Naphthalenediimide – A Unique Motif in Macrocyclic and Interlocked Supramolecular Structures
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2018-01-25 , DOI: 10.1002/adsc.201701362
Andreea Diac 1 , Mihaela Matache 2 , Ion Grosu 1 , Niculina D. Hădade 1
Affiliation  

This review presents a survey through macrocyclic and interlocked structures containing 1,4,5,8‐naphthalendiimide residues from the synthetic point of view and also illustrates the structural particularities that dictate their main applications in supramolecular, biological and materials chemistry. The paper is organised as a comprehensive description of macrocycles, cyclophanes, catenanes, rotaxanes and metallamacrocycles along with other types of supramolecular interlocked architectures. For each category, we present the synthetic approach, the structural investigation of their properties and the developed applications as semiconductors, energy storage devices, photovoltaics, artificial photosystems, sensors, catalysts or molecular machines.

中文翻译:

萘二酰亚胺–大环和互锁的超分子结构中的独特基序

这篇综述从合成的观点出发,对包含1,4,5,8-萘二酰亚胺残基的大环和互锁结构进行了调查,并阐明了决定其在超分子,生物学和材料化学中的主要应用的结构特殊性。本文的组织形式是对大环化合物,环烷,连环烷,轮烷和金属环以及其他类型的超分子互锁结构的全面描述。对于每种类别,我们都将介绍合成方法,其特性的结构研究以及作为半导体,能量存储设备,光伏,人造光系统,传感器,催化剂或分子机器的已开发应用。
更新日期:2018-01-25
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