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Iron‐Catalyzed Intramolecular Reductive Coupling of Unactivated Aldehydes and Arylalkenes with Isopropanol
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-12-06 , DOI: 10.1002/ajoc.201700622
Yan-Long Zheng 1 , Yan-Yao Liu 1 , Xue-Tao Xu 2 , Kun Zhang 2 , Mengchun Ye 1, 2
Affiliation  

FeCl3‐catalyzed intramolecular reductive coupling of unactivated aldehydes and arylalkenes with isopropanol as a terminal reductant under mild and easy‐to‐handle conditions has been developed. A series of five‐, six‐, seven‐ and eight‐membered carbocyclic alcohols were synthesized in moderate to excellent yields with high regioselectivities.

中文翻译:

铁催化未活化的醛和芳烃与异丙醇的分子内还原偶联

已开发出在温和且易于操作的条件下,FeCl 3催化的未活化醛和芳基烯烃与异丙醇作为末端还原剂的分子内还原偶联。合成了五元​​,六元,七元和八元碳环醇系列,具有中等至优异的产率,具有较高的区域选择性。
更新日期:2017-12-06
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