Metal–organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF‐based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.

中文翻译：

---

金属有机框架作为催化应用的平台

金属有机骨架（MOF），也称为多孔配位聚合物，代表了一类由有机连接剂和金属离子/簇构成的结晶多孔材料。MOF的独特功能，包括结构多样性和可定制性以及高表面积等，使它们成为在许多领域中潜在应用的高度通用的平台。本文概述了MOF催化的最新进展，包括MOF和基于MOF的材料的非均相催化，光催化和电催化。特别强调了催化剂中涉及的活性位。还讨论了与MOF及其相关催化材料相关的挑战，未来趋势和前景。