当前位置: X-MOL 学术Catal. Today › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Hydrodeoxygenation of acetophenone over a sulfonated carbon-supported ruthenium catalyst
Catalysis Today ( IF 5.2 ) Pub Date : 2017-12-02 , DOI: 10.1016/j.cattod.2017.11.034
Jingtuo Wang , Ying Zhang , Meng Zhang , Zhiqiang Wang , Minghui Zhang

A sulfonated active carbon supported Ru catalyst was prepared and tested in hydrodeoxygenation of acetophenone. The catalysts were characterized by XRD, TEM, N2 adsorption and NH3-TPD. The influences of reaction parameters on the conversion and selectivity were studied. An acetophenone conversion of 100% with total 90% selectivity of deoxygenated products was achieved at 150 °C over this catalyst, which was more active than the active carbon (AC) or SiO2 supported Ru catalysts. The enhanced performance of sulfonated AC supported Ru was attributed to the stronger acid sites and the better dispersion of Ru species. Moreover, such a catalyst was stable under the current reaction conditions and can be reused several times without obvious loss of activity.



中文翻译:

磺化碳载钌催化剂上苯乙酮的加氢脱氧

制备了磺化的活性炭负载的Ru催化剂,并在苯乙酮的加氢脱氧中进行了测试。通过XRD,TEM,N 2吸附和NH 3 -TPD对催化剂进行了表征。研究了反应参数对转化率和选择性的影响。在此催化剂上,在150℃下实现了100%的苯乙酮转化率和90%的脱氧产物选择性,它比活性炭(AC)或SiO 2负载的Ru催化剂更具活性。磺化AC负载Ru的性能增强归因于更强的酸位和Ru物种的更好分散性。而且,这种催化剂在当前的反应条件下是稳定的,并且可以重复使用几次而没有明显的活性损失。

更新日期:2017-12-02
down
wechat
bug