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Activation of Michael Acceptors by Halogen-Bond Donors
Synlett ( IF 1.7 ) Pub Date : 2017-12-01 , DOI: 10.1055/s-0036-1591841
Martin Breugst , Daniel von der Heiden , Eric Detmar , Robert Kuchta

Extending earlier studies on iodine catalysis, experimental investigations show that various halogen-bond donors can also be employed to accelerate the Michael addition between trans -crotonophenone and indole. Solvent as well as counteranion effects have been analyzed, and kinetic and computational investigations provide additional insights into the mode of activation.

中文翻译:

卤素键供体激活迈克尔受体

扩展碘催化的早期研究,实验研究表明,各种卤素键供体也可用于加速反式巴豆酮和吲哚之间的迈克尔加成。已经分析了溶剂和反阴离子效应,动力学和计算研究提供了对活化模式的额外见解。
更新日期:2017-12-01
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