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Enantioselective total synthesis of periconiasin A†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2017-12-01 00:00:00 , DOI: 10.1039/c7qo00952f
Zhixiong Zeng 1, 2, 3, 4, 5 , Cheng Chen 1, 2, 3, 4, 5 , Yandong Zhang 1, 2, 3, 4, 5
Affiliation  

A concise, enantioselective total synthesis of periconiasin A, a hybrid natural product, has been achieved, featuring a ring closing metathesis (RCM) reaction and a Suzuki coupling to secure a (Z,E,E)-skipped triene system and an intramolecular Diels–Alder (IMDA) reaction to construct the challenging 6–9 fused ring system.

中文翻译:

对映体全合成periconiasin A

一个简单的,对映体选择性的periconiasin A的全合成,一种杂合的天然产物,具有闭环易位(RCM)反应和Suzuki偶联,可确保(ZEE)跳过的三烯系统和分子内狄尔斯–Alder(IMDA)反应可构建具有挑战性的6–9稠环系统。
更新日期:2017-12-01
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