Rhodium-catalyzed intermolecular C(sp3)–H amination in a purely aqueous system,Green Chemistry

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Rhodium-catalyzed intermolecular C(sp3)–H amination in a purely aqueous system
Green Chemistry ( IF 9.3 ) Pub Date : 2017-11-28 00:00:00 , DOI: 10.1039/c7gc03149a
Xunbo Lu _{1,

2,

3,

4,

5} , Yufeng Shi _{1,

2,

3,

4,

5} , Fangrui Zhong _{1,

2,

3,

4,

5}

Affiliation

An efficient Rh-catalyzed intermolecular C(sp³)–H amination in a purely aqueous system is developed for the first time. This methodology features environmental benignity, broad substrate scope and versatility in late-stage functionalization of several biologically important molecules. Such an oxidation protocol provides easy access to various aliphatic amine derivatives in an efficient and sustainable manner.

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