Front Cover: Palladium Complexes of Carbazole‐Based Chalcogenaisophlorins: Synthesis, Structure, and Solid‐State NIR Absorption Spectra (ChemPlusChem 12/2017),ChemPlusChem

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Front Cover: Palladium Complexes of Carbazole‐Based Chalcogenaisophlorins: Synthesis, Structure, and Solid‐State NIR Absorption Spectra (ChemPlusChem 12/2017)
ChemPlusChem ( IF 3.0 ) Pub Date : 2017-11-28 , DOI: 10.1002/cplu.201700472
Chihiro Maeda ₁ , Kazuto Takaishi ₁ , Tadashi Ema ₁

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The cover picture shows the crystal packing of a palladium complex of a carbazole‐based chalcogenaisophlorin. Metalation planarizes the structure, inducing weak near infrared (NIR) absorption typical for antiaromatic porphyrinoids in solution. The sulfur‐ and selenium‐based complexes formed trimeric and dimeric stacked layered structures, respectively, and showed relatively strong NIR absorption in the solid state. More details can be found in the Communication by C. Maeda et al. on page 1368 in Issue 12, 2017 (DOI: 10.1002/cplu.201700430).

中文翻译：

封面：基于咔唑的硫族配糖蛋白的钯配合物：合成，结构和固态近红外吸收光谱（ChemPlusChem 12/2017）

封面图片显示了基于咔唑的硫属元素金属硫蛋白的钯配合物的晶体堆积。金属化使结构平面化，从而导致溶液中抗芳香族卟啉类化合物具有典型的弱近红外（NIR）吸收能力。硫和硒基络合物分别形成三聚体和二聚体堆叠的层状结构，并在固态下显示出较强的近红外吸收。可以在C. Maeda等人的来文中找到更多详细信息。就在第12期，2017年1368页（：10.1002 / cplu.201700430 DOI）。

更新日期：2017-11-28

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