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Fluorous gels of a fluorous alcohol using a low molecular weight anthracene organogelator
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2017-11-28 , DOI: 10.1016/j.jfluchem.2017.11.011 Hiroki Miyajima , Maria Carmelita Z. Kasuya , André Del Guerzo , Jean-Marc Vincent , Kenichi Hatanaka
中文翻译:
使用低分子量蒽有机胶凝剂的氟代醇的氟凝胶
更新日期:2017-11-28
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2017-11-28 , DOI: 10.1016/j.jfluchem.2017.11.011 Hiroki Miyajima , Maria Carmelita Z. Kasuya , André Del Guerzo , Jean-Marc Vincent , Kenichi Hatanaka
A fluorous gel was prepared using 2,3-di-n-decyloxyanthracene (DDOA), a low-molecular mass gelator (LMMG) for alcohols, and 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol. The fluorous gel is thermoreversible and its melting temperature can be adjusted by changing the concentration of DDOA. Interestingly, a reduction of the critical concentration of gelation and a tuning of the melting temperature around 37 °C can be achieved by adding the non-gelling analogue 2,3-dimethoxyanthracene (DMOA) to DDOA.
中文翻译:
使用低分子量蒽有机胶凝剂的氟代醇的氟凝胶
使用2,3-二正癸氧基蒽(DDOA),一种用于醇类的低分子质量胶凝剂(LMMG)和2,2,3,3,4,4,5,5,6制备氟代凝胶6,7,7-十二氟-1-庚醇。氟凝胶是可热逆的,可以通过改变DDOA的浓度来调节其熔融温度。有趣的是,通过将非胶凝类似物2,3-二甲氧基蒽(DMOA)添加到DDOA中,可以降低临界胶凝浓度并在37°C左右调节熔融温度。