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Dual combining transition metal hybrid nanoparticles for ammonia borane hydrolytic dehydrogenation
Applied Catalysis A: General ( IF 4.7 ) Pub Date : 2017-11-26 , DOI: 10.1016/j.apcata.2017.11.022
Bilge Coşkuner Filiz , Aysel Kantürk Figen , Sabriye Pişkin

A new hybrid of nanoparticles designed to enable efficient catalysis for hydrogen generation (NPs) include a dual combination of Co, Ni, and Cu transition metals. These nanoparticles are made by altering metals and molar ratios (x: 0.25, 0.50, and 0.75) and synthesized for hydrogen generation by hydrolytic dehydrogenation of ammonia borane (NH3BH3). A synergistic effect of dual combination on the induction period and dehydrogenation rate (DR) is found. Kinetic interpretation and thermodynamic studies demonstrate that the Co0.50Cu0.50/NPs catalyst shows superior activation (DR = 10.56 l H2 min−1.g−1cat and Ea = 38.12 kJ mol−1) with a synergistic effect and meet the criteria of The United States Department of Energy (DOE) targets for onboard hydrogen production systems for light-duty vehicles.



中文翻译:

双组合过渡金属杂化纳米粒子用于氨硼烷水解脱氢

一种新型的纳米颗粒杂化物,旨在有效催化氢生成(NP),包括Co,Ni和Cu过渡金属的双重组合。这些纳米粒子是通过改变金属和摩尔比(x:0.25、0.50和0.75)制成的,并通过氨硼烷(NH 3 BH 3)的水解脱氢合成氢。发现双重组合对诱导期和脱氢率(DR)具有协同作用。动力学解释和热力学研究表明,Co 0.50 Cu 0.50 / NPs催化剂显示出优异的活化性(DR = 10.56 l H 2  min -1 .g -1 cat和E a  = 38.12 kJ mol-1)具有协同作用,并符合美国能源部(DOE)轻型车辆车用制氢系统目标的标准。

更新日期:2017-11-26
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