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One-pot synthesis of Ni nanoparticle/ordered mesoporous carbon composite electrode materials for electrocatalytic reduction of aromatic ketones
Nanoscale ( IF 5.8 ) Pub Date : 2017-10-19 00:00:00 , DOI: 10.1039/c7nr06602c Zhi-Xia Zhang 1, 2, 3, 4, 5 , Yupu Liu 6, 7, 8, 9, 10 , Wang-Jun Meng 1, 2, 3, 4, 5 , Jinxiu Wang 6, 7, 8, 9, 10 , Wei Li 6, 7, 8, 9, 10 , Huan Wang 1, 2, 3, 4, 5 , Dongyuan Zhao 6, 7, 8, 9, 10 , Jia-Xing Lu 1, 2, 3, 4, 5
Nanoscale ( IF 5.8 ) Pub Date : 2017-10-19 00:00:00 , DOI: 10.1039/c7nr06602c Zhi-Xia Zhang 1, 2, 3, 4, 5 , Yupu Liu 6, 7, 8, 9, 10 , Wang-Jun Meng 1, 2, 3, 4, 5 , Jinxiu Wang 6, 7, 8, 9, 10 , Wei Li 6, 7, 8, 9, 10 , Huan Wang 1, 2, 3, 4, 5 , Dongyuan Zhao 6, 7, 8, 9, 10 , Jia-Xing Lu 1, 2, 3, 4, 5
Affiliation
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A simple one-pot synthesis of Ni nanoparticle/ordered mesoporous carbon composite electrode materials is demonstrated for electrosynthesis for the first time. The obtained nanocomposites have uniform mesopore sizes (3.0–3.7 nm), large specific surface areas (506–633 m2 g−1), high pore volumes (0.28–0.38 cm3 g−1), well-graphitized carbon frameworks, and uniformly dispersed Ni nanoparticles (7–15 nm) embedded in the carbon pore walls. The prepared materials show very high performance in the selective (∼84%) electrocatalytic reduction of aromatic ketones into alcohols (∼79%).
中文翻译：
一锅法合成镍纳米粒子/有序介孔碳复合电极材料用于电催化还原芳族酮
首次展示了用于电合成的简单的一锅法合成镍纳米粒子/有序介孔碳复合电极材料。获得的纳米复合材料具有均匀的中孔尺寸（3.0-3.7 nm），大比表面积（506-633 m 2 g -1），高孔体积（0.28-0.38 cm 3 g -1），石墨化良好的碳骨架和均匀分散的镍纳米粒子（7–15 nm）嵌入碳孔壁中。所制备的材料在将芳族酮选择性催化（约84％）电催化还原为醇类（约79％）时表现出极高的性能。
更新日期：2017-11-23
中文翻译：
一锅法合成镍纳米粒子/有序介孔碳复合电极材料用于电催化还原芳族酮
首次展示了用于电合成的简单的一锅法合成镍纳米粒子/有序介孔碳复合电极材料。获得的纳米复合材料具有均匀的中孔尺寸（3.0-3.7 nm），大比表面积（506-633 m 2 g -1），高孔体积（0.28-0.38 cm 3 g -1），石墨化良好的碳骨架和均匀分散的镍纳米粒子（7–15 nm）嵌入碳孔壁中。所制备的材料在将芳族酮选择性催化（约84％）电催化还原为醇类（约79％）时表现出极高的性能。
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