Abstract

The plethora of transformations attainable by the transition-metal-catalyzed reactions of arynes has found immense contemporary interest in the scientific community. This review highlights the scope and importance of transition-metal-catalyzed aryne reactions in the field of synthetic organic chemistry reported to date. It covers transformations achieved by the combination of arynes and various transition metals, which provide a facile access to a biaryl motif, fused polycyclic aromatic compounds, different novel carbocycles, various heterocycles, and complex natural products.

1 Introduction

2 Insertion of Arynes

3 Annulation of Arynes

4 Cycloaddition of Arynes

5 Multicomponent Reactions of Arynes

6 Miscellaneous Reactions of Arynes

7 Total Synthesis of Natural Products Using Arynes

8 Conclusion

The plethora of transformations attainable by the transition-metal-catalyzed reactions of arynes has found immense contemporary interest in the scientific community. This review highlights the scope and importance of transition-metal-catalyzed aryne reactions in the field of synthetic organic chemistry reported to date. It covers transformations achieved by the combination of arynes and various transition metals, which provide a facile access to a biaryl motif, fused polycyclic aromatic compounds, different novel carbocycles, various heterocycles, and complex natural products.

1 Introduction

2 Insertion of Arynes

3 Annulation of Arynes

4 Cycloaddition of Arynes

5 Multicomponent Reactions of Arynes

6 Miscellaneous Reactions of Arynes

7 Total Synthesis of Natural Products Using Arynes

8 Conclusion

中文翻译：

---

涉及芳烃的过渡金属催化反应

摘要

在芳烃的过渡金属催化的反应中，可以进行大量的转化，这在科学界引起了极大的当代兴趣。这篇综述突出了迄今为止报道的在合成有机化学领域中过渡金属催化的芳烃反应的范围和重要性。它涵盖了通过芳烃和各种过渡金属的组合而实现的转化，这些过渡金属可轻松获得联芳基，稠合的多环芳族化合物，不同的新型碳环化合物，各种杂环和复杂的天然产物。

1引言

2插入Arynes

3 Arynes的周年纪念

4 Arynes的环加成

5芳烃的多组分反应

6 Arynes的其他反应

7使用Arynes进行天然产物的全合成

8结论

在芳烃的过渡金属催化的反应中，可以进行大量的转化，这在科学界引起了极大的当代兴趣。这篇综述突出了迄今为止报道的在合成有机化学领域中过渡金属催化的芳烃反应的范围和重要性。它涵盖了通过芳烃和各种过渡金属的组合而实现的转化，这些过渡金属可轻松获得联芳基，稠合的多环芳族化合物，不同的新型碳环化合物，各种杂环和复杂的天然产物。

1引言

2插入Arynes

3 Arynes的周年纪念

4 Arynes的环加成

5芳烃的多组分反应

6 Arynes的其他反应

7使用Arynes进行天然产物的全合成

8结论