Are There Carbenes in N-Heterocyclic Carbene Organocatalysis?,Angewandte Chemie International Edition

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Are There Carbenes in N-Heterocyclic Carbene Organocatalysis?
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-22 11:06:44 , DOI: 10.1002/anie.201708305
Sascha Gehrke _{1,

2} , Oldamur Hollóczki ₁

Affiliation

Another alternative: A novel reaction pathway for N-heterocyclic carbene organocatalysis has been identified. In this process, proton transfer and the binding of the substrate to the catalyst occur simultaneously in a single elementary reaction step, without the formation of a free carbene molecule in the reaction mixture.

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