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Bifurcated Nickel-Catalyzed Functionalizations: Heteroarene C−H Activation with Allenes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-22 04:18:35 , DOI: 10.1002/anie.201709087
Sachiyo Nakanowatari 1 , Thomas Müller 1 , João C. A. Oliveira 1 , Lutz Ackermann 1
Affiliation  

Facile C−H activation: Bifurcated nickel(0)-catalyzed C−H allylations, alkenylations, and dienylations have been accomplished by versatile hydroarylations of allenes with full control of regio- and chemoselectivity. The scope of the reaction covers a variety of imidazole and purine derivatives.

中文翻译:

分叉的镍催化的功能化:杂芳烃CH活化与Allenes。

便捷的CH活化:通过多烯键的多氢加氢芳基化并完全控制区域和化学选择性,可实现镍(0)分叉的镍(0)催化的CH H烯丙基化,烯基化和二烯基化。反应范围包括各种咪唑和嘌呤衍生物。
更新日期:2017-11-22
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