Bifurcated Nickel-Catalyzed Functionalizations: Heteroarene C−H Activation with Allenes,Angewandte Chemie International Edition

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Bifurcated Nickel-Catalyzed Functionalizations: Heteroarene C−H Activation with Allenes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-22 04:18:35 , DOI: 10.1002/anie.201709087
Sachiyo Nakanowatari ₁ , Thomas Müller ₁ , João C. A. Oliveira ₁ , Lutz Ackermann ₁

Affiliation

Facile C−H activation: Bifurcated nickel(0)-catalyzed C−H allylations, alkenylations, and dienylations have been accomplished by versatile hydroarylations of allenes with full control of regio- and chemoselectivity. The scope of the reaction covers a variety of imidazole and purine derivatives.

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