Temperature-Mediated Template Release: Facile Growth of Copper(I) Mixed Ethynediide/Isopropylethynide Nanoclusters,Angewandte Chemie International Edition

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Temperature-Mediated Template Release: Facile Growth of Copper(I) Mixed Ethynediide/Isopropylethynide Nanoclusters
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-22 04:18:08 , DOI: 10.1002/anie.201708760
Leon Li-Min Zhang ₁ , Thomas C. W. Mak ₁

Affiliation

Template release: Temperature variation triggers the release of ethynediide C₂²⁻ from isopropylacetylene through concomitant C−H/C−C bond cleavage, leading to formation of Cu^I mixed ethynediide/alkynide nanoclusters. Synthesis of {C₂²⁻⊂Cu₂₄}, {6 C₂²⁻⊂Cu₄₈}, and {18 C₂²⁻⊂Cu₉₂} establishes a class of tunable nanostructures where the increasing number of ethynediide bestows nuclearity expansion and structural diversity.

中文翻译：

温度介导的模板释放：铜（I）混合乙炔/异丙乙炔纳米簇的容易生长

模板释放：温度变化通过伴随的C-H / C-C键裂解触发乙炔C ₂^2-从异丙基乙炔中释放，导致形成Cu ^I混合乙炔/炔烃纳米团簇。{C的合成₂^2- ⊂Cu ₂₄ }，{6个C ₂^2- ⊂Cu ₄₈ }和{18℃ ₂^2- ⊂Cu ₉₂ }建立类的可调谐纳米结构，其中越来越多ethynediide禀赋核性膨胀和结构多样性。

更新日期：2017-11-22

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