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The Quest for Mononuclear Gold(II) and Its Potential Role in Photocatalysis and Drug Action
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-22 03:48:29 , DOI: 10.1002/anie.201708349
Katja Heinze 1
Affiliation  

Gold(II) plays a key role in artificial photosynthesis systems, with gold(III) moieties acting as electron acceptors, as well as in gold photoredox catalysis and radical chemistry. This Minireview provides a concise summary of unambiguously characterized mononuclear gold(II) complexes along with evolving structural motifs and reactivity patterns. Developments in the fields of photosynthesis, photocatalysis, and potential modes of action of anticancer drugs are outlined.

中文翻译:

寻求单核金(II)及其在光催化和药物作用中的潜在作用

金(II)在人造光合作用系统中起着关键作用,其中金(III)部分充当电子受体,并且在金光氧化还原催化和自由基化学中。这份Minireview提供了明确表征的单核金(II)配合物以及不断发展的结构图案和反应性模式的简明摘要。概述了光合作用,光催化和抗癌药物潜在作用方式的发展。
更新日期:2017-11-22
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