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Oxidation of Organic Molecules with a Redox-Active Guanidine Catalyst
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-11-22 03:20:35 , DOI: 10.1002/anie.201709809
Ute Wild 1 , Florian Schön 1 , Hans-Jörg Himmel 1
Affiliation  

Green and organic: Owing to the combination of high Brønsted basicity and electron-donor properties, redox-active guanidines are superior organic redox catalysts, as herein shown for the first catalytic oxidation reactions of 3,5-di-tert-butylcatechol, benzoin, and 2,4-di-tert-butylphenol with dioxygen.

中文翻译:

氧化还原活性胍催化剂氧化有机分子

绿色和有机:由于高布朗斯台德碱度和电子给体性质的结合,氧化还原活性胍是优良的有机氧化还原催化剂,如本文所示,它是3,5-二叔丁基邻苯二酚,安息香的首次催化氧化反应,和2,4-二叔丁基苯酚加双氧。
更新日期:2017-11-22
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