Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-11-22 03:15:39 , DOI: 10.1002/anie.201710358
Alfredo Rosas-Sánchez ₁ , Isabel Alvarado-Beltran ₁ , Antoine Baceiredo ₁ , Nathalie Saffon-Merceron ₂ , Stéphane Massou ₂ , Daisuke Hashizume ₃ , Vicenç Branchadell ₄ , Tsuyoshi Kato ₁

Affiliation

A silanone substituted by bulky amino and phosphonium bora-ylide substituents has been synthesized and isolated in crystalline form. Thanks to the exceptionally strong electron-donating phosphonium-bora-ylide substituent, the lifetime is dramatically extended (t_1/2=4 days). The interaction with a weak Lewis acid such as MgBr₂ increases further its stability, and no degradation of silanone was observed after 3 weeks at room temperature.

中文翻译：

环（氨基）（硼酸内鎓盐）甲硅酮：显着的常温持久性硅酮

已经合成并以结晶形式分离了被笨重的氨基和bo硼烷基内酯取代基取代的硅酮。得益于特别强大的供电子phospho-硼酸内酯取代基，使用寿命大大延长（t _1/2 = 4天）。与弱路易斯酸（例如MgBr _2）的相互作用进一步提高了其稳定性，并且在室温下放置3周后未观察到硅酮的降解。

更新日期：2017-11-22

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11