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Efficient Solution- and Solid-State Fluorescence for a Series of 7-Diethylaminocoumarin Amide Compounds
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-11-22 03:00:34 , DOI: 10.1002/ajoc.201700555
Yatong Sun 1 , Yunhui Sun 1 , Songfang Zhao 1 , Duxia Cao 1 , Ruifang Guan 1 , Zhiqiang Liu 2 , Xueying Yu 1 , Xun Zhao 1
Affiliation  

7-Heaven: A series of 7-diethylaminocoumarin amides that exhibited strong fluorescence in THF, high-viscosity glycerol solution, and the solid state (powder) have been synthesized. The phenyl amide displayed enhanced fluorescence in the solid state relative to that in THF. The high-viscosity glycerol and solid states may restrict the rotation of the 7-diethylamino group, thereby leading to nonradiative deactivation and fluorescence enhancement.

中文翻译:

一系列7-二乙基氨基香豆素酰胺化合物的高效溶液和固态荧光

7-天堂:已经合成了一系列在THF,高粘度甘油溶液和固态(粉末)中显示出强荧光的7-二乙基氨基香豆素酰胺。相对于THF,苯基酰胺在固态下显示出增强的荧光。高粘度的甘油和固态会限制7-二乙氨基的旋转,从而导致非辐射失活和荧光增强。
更新日期:2017-11-22
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