Imidazolium- and Triazine-Based Porous Organic Polymers for Heterogeneous Catalytic Conversion of CO2 into Cyclic Carbonates,ChemSusChem

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Imidazolium- and Triazine-Based Porous Organic Polymers for Heterogeneous Catalytic Conversion of CO2 into Cyclic Carbonates
ChemSusChem ( IF 7.5 ) Pub Date : 2017-11-22 03:56:46 , DOI: 10.1002/cssc.201701821
Hong Zhong _{1,

2} , Yanqing Su _{1,

2} , Xingwei Chen ₂ , Xiaoju Li _{1,

2} , Ruihu Wang ₂

Affiliation

POP stars: Porous organic polymers (POPs) containing imidazolium and triazine units are presented here. The roles of task-specific components such as triazine, imidazolium, hydroxyl, and counter anions in CO₂ absorption and catalytic conversion are illustrated. The catalytic systems show high catalytic activity and excellent recyclability in solvent- and additive-free cycloaddition reaction of CO₂ with epoxides.

中文翻译：

基于咪唑和三嗪的多孔有机聚合物，可将CO2多相催化转化为环状碳酸酯

POP明星：此处介绍了含咪唑和三嗪单元的多孔有机聚合物（POP）。说明了任务特定的组分（例如三嗪，咪唑鎓，羟基和抗衡阴离子）在CO ₂吸收和催化转化中的作用。该催化体系在CO ₂与环氧化物的无溶剂和无添加剂的环加成反应中显示出高催化活性和出色的可回收性。

更新日期：2017-11-22

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